Novel monoanionic diphenate-nicotinamide/N,N-diethylnicotinamide complexes of NiII, ZnII. Synthesis, structural investigations and hydrogen adsorption study
Yazarlar (5)
Prof. Dr. Zarife Sibel ŞAHİN Sinop Üniversitesi, Türkiye
Arş. Gör. Ömer Yurdakul Hitit Üniversitesi, Türkiye
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Fatih Akkurt Gazi Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2020)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 12-2020
Kabul Tarihi Yayınlanma Tarihi 01-10-2020
Cilt / Sayı / Sayfa 1218 / 1 / 128514– DOI 10.1016/j.molstruc.2020.128514
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0022286020308395
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Mixed ligand complexes containing monoanionic diphenate (Hdiphen-), dianionic diphenate (diphen2−)-nicotinamide (nic)/N,N-diethylnicotinamide (denic) ligands of Ni(II) and Zn(II) transition metal cations were synthesized, their structural characterizations and molecular simulation for hydrogen adsorption were performed. It is the salt type coordination compound of the Ni(II) complex, complementing the metal octahedral environment with 2 mol of nic and 4 mol of aqua ligands. Two moles of Hdiphen- ligand is monoanionic located outside the coordination sphere and provides the charge equivalence of the complex. In the Zn(II) complex structure, denic and diphen2− ligand is located within the coordination sphere. In the Zn(II) coordination compound structure, diphen2− ligands, which are located in the structure of a bridge between two different metal centres, make the structure polymeric. The binding properties of …
Anahtar Kelimeler
Diphenic acid | Energy storage materials | Hydrogen adsorption | Metal complexes | Metal-organic materials (MOMs) | Nicotinamide