The synthesis of heteroleptic cyanometallate aminopyridine complexes and an investigation into their structural properties with various spectroscopic methods
Yazarlar (2)
Zeki Kartal
Retired Professor Of Atomic And Molecular Physics, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2021)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 01-2021
Cilt / Sayı / Sayfa 1227 / 1 / 129514–0 DOI 10.1016/j.molstruc.2020.129514
Makale Linki http://dx.doi.org/10.1016/j.molstruc.2020.129514
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
In this study, three new transition metal(II) complexes consisting of zinc(II), mercury(II) atoms, cyanide group (CN), 3-aminopyridine (3AP) and 4-aminopyridine (4AP) ligand molecules were successfully synthesized in a single crystal form. The formulas of these newly synthesized heteroleptic cyanometalate aminopyridines complexes are given as [Zn(II)(3AP)2(CN)2], [Zn(II)(4AP)2(CN)2] and [Hg(II)(4AP)2(CN)2]. The crystal structures of these heteroleptic cyanometalate complexes were characterized by spectral analysis including single crystal X-ray diffraction techniques, FT-IR, and thermal analysis. The FT-IR and single crystal XRD spectra of these complexes were recorded in the 3750–250 cm−1 wavenumber range and in the region of about 3–29°, respectively. In addition, the thermal analysis curves of these complexes were recorded in the temperature range of 40–850 ℃ using TG, DTG, and DSC methods …
Anahtar Kelimeler
3-aminopyridine | 4-aminopyridine | Cyano ligand | FT-IR spectra | Heteroleptic cyanometalate complexes | Single-crystal X-ray diffraction analysis