Mn(II) and Co(II) mixed-ligand coordination compounds with acesulfame and 3-aminopyridine: synthesis and structural properties
Yazarlar (4)
Arş. Gör. Ömer Yurdakul Hitit Üniversitesi, Türkiye
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Doç. Dr. Demet Özer Hacettepe Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Coordination Chemistry (Q3) | ||
| Dergi ISSN | 0095-8972 Dergi Bilgileri (2021) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Kabul Tarihi | 16-12-2020 | Yayınlanma Tarihi | 09-03-2021 |
| Cilt / Sayı / Sayfa | 74 / 7 / 1168–1180 | DOI | 10.1080/00958972.2021.1888083 |
| Makale Linki | http://dx.doi.org/10.1080/00958972.2021.1888083 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Two mixed ligand complexes containing acesulfame (acs) and 3-aminopyridine (3-ap) ligands of Mn(II) and Co(II) were synthesized. The obtained compounds were characterized by various analysis methods. The geometries of complexes, C18H28MnN6O12S2 (1) and C18H32CoN6O14S2 (2), are distorted octahedra. Coordination of metal cations is provided by two molecules of 3-ap and four water ligands. In both structures, the 2+ charge of the metal required two monoanionic acs molecules located outside the coordination sphere. Complex 1 contains no hydrate water, while 2 contains two molecules of hydrate water. The crystal system of 1 is monoclinic and space group P21/c, while the crystal system of 2 is triclinic and space group P-1. Data on the removal of hydrate and crystalline waters in structures from thermal analysis curves support the described molecular structures. The bending vibrations of the … |
| Anahtar Kelimeler |
| 3-aminopyridine | Acesulfame | crystal structures | metal complexes | thermal analysis |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 13 |
| Scopus | 13 |
| Google Scholar | 17 |