Facile solvothermal syntheses of isostructural lanthanide(III) formates: Photocatalytic, photoluminescent chemosensing properties, and proficient precursors for metal oxide nanoparticles
Yazarlar (8)
Sidra Farid
Government College University Lahore, Pakistan
Saima Ameen
Government College University Lahore, Pakistan
Shahzad Sharif
Government College University Lahore, Pakistan
Madiha Tariq
Government College University Lahore, Pakistan
Israr Ahmad Kundi
Government College University Lahore, Pakistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Muhammd Hassan Sayyad
Ghulam Ishaq Khan Institute Of Engineering Sciences And Technology, Pakistan
Islam Ullah Khan
University Of Mianwali, Pakistan
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Coordination Chemistry (Q3)
Dergi ISSN 0095-8972 Dergi Bilgileri (2021)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2021
Kabul Tarihi 18-02-2021 Yayınlanma Tarihi 13-04-2021
Cilt / Sayı / Sayfa 74 / 9 / 1700–1719 DOI 10.1080/00958972.2021.1907843
Makale Linki http://dx.doi.org/10.1080/00958972.2021.1907843
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Three isostructural lanthanide coordination polymers (CPs) with the formula C3H3LnO6 [Ln = Pr (1), Ce (2), and Dy (3)] were solvothermally synthesized by self-assembly of lanthanide(III) and in-situ generated methanoic acid by the hydrolysis of N,N-dimethyl formamide. These CPs were characterized by FTIR, elemental analysis, PXRD, and single crystal analysis. The metal centered luminescence properties of these coordination polymers revealed that only the dysprosium based CP exhibited significant luminescence, and it was found to be selective for chemosensing of picric acid. 3 showed quenching efficiency of 89.7% with KSV value of 2.89 × 104 M−1. These coordination polymers were also exploited as photocatalysts for degradation of methylene blue, and the dysprosium based CP proved to be a fantastic photocatalyst with the degradation activity of 92% owing to its effective electronic transitions. The …
Anahtar Kelimeler
chemosensing | Lanthanide formats | luminescence | nanoparticles | photocatalyst