Two-Dimensional Heteronuclear Coordination Polymers Constructed by Cyanide and 3-(2-Aminoethyl)pyridine Ligands
Yazarlar (4)
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Dr. Öğr. Üyesi Elvan Sayın Turkish Standard Institution (Tse), Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Inorganic and Organometallic Polymers and Materials (Q2)
Dergi ISSN 1574-1443 Dergi Bilgileri (2020)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2020
Kabul Tarihi 24-08-2020 Yayınlanma Tarihi 03-09-2020
Cilt / Sayı / Sayfa 31 / 1 / 112–120 DOI 10.1007/s10904-020-01724-1
Makale Linki http://dx.doi.org/10.1007/s10904-020-01724-1
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Two new heteronuclear (Ni/Cd and Pd/Cd) 2D coordination polymers formulated as namely {[Cd(μ-3aepy)2Ni(μ-CN)2(CN)2]⋅2H2O}n (1) and [Cd(3aepy)Pd(μ4-CN)4]n (2) (3aepy = 3-(2-aminoethyl)pyridine) were obtained and determined using different techniques (FT-IR and Raman spectroscopies, single crystal X-ray diffraction, elemental, SEM–EDX and thermal analyses). Single crystal X-ray study of the complexes revealed that the Ni(II) and Pd(II) ions are coordinated with four cyanide-carbon atoms in square planar geometries. The Cd(II) ions are bridged by 3aepy ligands to generate [Cd2(3aepy)2]2+ cation and adjacent cations are further linked to cyanide ligands from [Ni(μ-CN)4]2− anion, generating corrugated rectangular grid-like 2D sheets in 1. Whereas, the Cd(II) and Pd(II) ions are bridged by cyanide ligands, generating corrugated rectangular grid-like 2D sheets in 2. The Cd1 is possessed the distorted octahedral coordination geometry with six nitrogen atoms from two 3aepy and four cyanide ligands. The Cd2 is coordinated by four nitrogen atoms from cyanide ligands to form a square-planar geometry. Furthermore, the most remarkable properties of the complexes are the existence of the intermolecular C–H⋯M interactions between M(II) and hydrogen atoms of the 3aepy ligands (M(II) = Ni and Pd).
Anahtar Kelimeler
3-(2-aminoethyl)pyridine complex | Cyanide complex | C–H⋯Ni interaction | C–H⋯Pd interaction | Tetracyanonickelate(II) complex | Tetracyanopalladate(II) complex
Pdf İndir
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Two-Dimensional Heteronuclear Coordination Polymers Constructed by Cyanide and 3-(2-Aminoethyl)pyridine Ligands

Paylaş

İletişim
  • Korucuk Mahallesi Selanik Caddesi No:21
  • unis@sinop.edu.tr 0 368 271 57 57
Sosyal Media
Talentsoft Yazılım Talent Yazılım
Tasarım ve Programlama #2025