Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water
Yazarlar (2)
Zeki Kartal
Retired Professor Of Atomic And Molecular Physics, Türkiye
Retired Professor Of Atomic And Molecular Physics, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Turkish Journal of Chemistry (Q3) | ||
| Dergi ISSN | 1300-0527 Dergi Bilgileri (2021) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Cilt / Sayı / Sayfa | 45 / 3 / 616–633 | DOI | 10.3906/kim-2011-29 |
| Makale Linki | http://dx.doi.org/10.3906/kim-2011-29 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| In this study, synthesis of two new heteronuclear tetracyanonickelate (II) clathrates based on 4-aminopyridine (4AP) and guest water (H2O) molecule and investigation of their structural properties were reported. These clathrates were characterized by using vibration spectroscopy, elemental, thermal analysis and single crystal X-ray diffraction (SC-XRD) techniques. Examining the elemental and spectral data of these clathrates, it was observed that the formulas [Zn (II)(4AP) 2Ni (μ-CN) 2 (CN) 2]· 6H2O and [Cu (II)(4AP) 4Ni (μ-CN) 2 (CN) 2]· H2O were defined their structures. General information about the structural properties of these clathrates in single crystal form has been obtained by considering the changes in the characteristic peaks of the cyanide group and the 4AP that formed them. The thermal behaviors of these clathrates were obtained by examining the temperature-dependent changes of their masses. The magnetic susceptibilities of these clathrates in single crystal form were measured with a Gouy balance. According to the data obtained using SC-XRD technique, the heterometallic [Zn (II)(4AP) 2Ni (μ-CN) 2 (CN) 2]· 6H2O compound has Cmcm and the heterometallic [Cu (II)(4AP) 4Ni (μ-CN) 2 (CN) 2]· H2O compound has crystal structures in the C2/c space group. |
| Anahtar Kelimeler |
| 4-aminopyridine | Hofmann-type clathrates | Hofmann-type-like clathrates | Single crystal X-Ray diffraction (SC-XRD) analysis | Vibration spectra |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 7 |
| Google Scholar | 11 |