Unprecedented deca-, penta- and poly-heteronuclear complexes with hexacyanometallates and 2-(hydroxymethyl)pyridine
Yazarlar (4)
Dr. Öğr. Üyesi Elvan Sayın Turkish Standard Institution (Tse), Türkiye
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q1) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2021) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-12-2021 |
| Cilt / Sayı / Sayfa | 210 / 1 / 115535–0 | DOI | 10.1016/j.poly.2021.115535 |
| Makale Linki | http://dx.doi.org/10.1016/j.poly.2021.115535 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The reactions of hexacyanometallates (Fe(III) and Co(III)) and 2-(hydroxymethyl)pyridine (hmpy) with ZnCl2 and CdCl2 affords the decanuclear [Cd6(hmpy)12Fe2(μ-CN)8(CN)4Fe2(μ-CN)4(CN)8] complex (1), the pentanuclear [Cd3(hmpy)6Co2(μ-CN)6(CN)6] cage complex (2) and the 3D framework [Zn(hmpy)2Zn2(hmpy)2Co2(µ-CN)8(CN)4]n (3). These new cyanide-bridged heteronuclear complexes have been characterised by FT-IR and Raman spectra, together with thermal and elemental analyses. Their structures have been determined by single crystal X-ray diffraction (SC-XRD) and powder X-ray diffraction (PXRD) analyses. In 1, the Cd(II) and Fe(III) centers are arranged alternately at the four corners of a rhombic core, and the cyanide ligands coordinate to the four metal centers of this core in the bridging mode. Adjacent tetranuclear rhombic cores further extend to a decaheteronuclear cluster structure via … |
| Anahtar Kelimeler |
| 2-(Hydroxymethyl)pyridine complex | Coordination polymer | Heteronuclear complex | Hexacyanocobaltate(III) complex | Hexacyanoferrate(III) complex |
Science Direct
Unprecedented deca-, penta- and poly-heteronuclear complexes with hexacyanometallates and 2-(hydroxymethyl)pyridine
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| Atıf Sayıları | |
| Web of Science | 6 |
| Scopus | 6 |
| Google Scholar | 6 |