Novel coordination compounds of alkaline earth metals with coumarilic acid. Synthesis and characterization
Yazarlar (4)
Emrah Karaer
Hitit University, Türkiye
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
Prof. Dr. Zarife Sibel ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2021)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2021
Kabul Tarihi Yayınlanma Tarihi 01-11-2021
Cilt / Sayı / Sayfa 1244 / 1 / 130970–0 DOI 10.1016/j.molstruc.2021.130970
Makale Linki http://dx.doi.org/10.1016/j.molstruc.2021.130970
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
In this study, novel coordination compounds of coumarilic acid with 2A group alkaline earth metal cations [Mg2+ (1), Ca2+ (2), Sr2+ (3) and Ba2+(4)] were synthesized and structural characterized. The structural properties of the new molecules obtained were studied by melting point, elemental analysis, infrared spectroscopy, single crystal x-ray diffraction (SC-XRD), powder x-ray diffraction (P-XRD) spectroscopy. In addition, the thermal stability of the compounds were examined by thermal analysis (TGA/DTA) curves in an inert nitrogen atmosphere. When the structural properties of the molecules were examined, it was seen that the structure numbered 1 {[Mg(H2O)6].2(C9H5O3)} differed from the others and it was a kind of aqua complex. The coumarilate anions anionically located outside the coordination sphere serve as the counter-ion of the molecule. It has been determined that the other structures 2 {μ-(H2O)2[C …
Anahtar Kelimeler
Alkaline earth metals | Coumarilic acid | Coumarin-3-carboxylic acid | Single crystal | Thermal analysis
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 6
Scopus 6
Google Scholar 5
Novel coordination compounds of alkaline earth metals with coumarilic acid. Synthesis and characterization

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