Two‑Dimensional Heteronuclear Coordination Polymers Constructed by Cyanide and 3‑(2‑Aminoethyl)pyridine Ligands
Yazarlar (4)
Prof. Dr. Okan Zafer Yeşilel Türkiye
Dr. Öğr. Üyesi Elvan Sayın Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials (Q2) | ||
| Dergi ISSN | 1574-1443 Dergi Bilgileri (2021) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Cilt / Sayı / Sayfa | 31 / 1 / 112–120 | DOI | – |
| Makale Linki | https://link.springer.com/article/10.1007/s10904-020-01724-1 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| Two new heteronuclear (Ni/Cd and Pd/Cd) 2D coordination polymers formulated as namely {[Cd(μ-3aepy)2Ni(μ-CN)2(CN)2]⋅2H2O}n (1) and [Cd(3aepy)Pd(μ4-CN)4]n (2) (3aepy = 3-(2-aminoethyl)pyridine) were obtained and determined using different techniques (FT-IR and Raman spectroscopies, single crystal X-ray diffraction, elemental, SEM–EDX and thermal analyses). Single crystal X-ray study of the complexes revealed that the Ni(II) and Pd(II) ions are coordinated with four cyanide-carbon atoms in square planar geometries. The Cd(II) ions are bridged by 3aepy ligands to generate [Cd2(3aepy)2]2+ cation and adjacent cations are further linked to cyanide ligands from [Ni(μ-CN)4]2− anion, generating corrugated rectangular grid-like 2D sheets in 1. Whereas, the Cd(II) and Pd(II) ions are bridged by cyanide ligands, generating corrugated rectangular grid-like 2D sheets in 2. The Cd1 is possessed the … |
| Anahtar Kelimeler |
