Novel zinc compound with thiosemicarbazone of glyoxylic acid: Synthesis, crystal structure, and bioactivity properties
Yazarlar (7)
Mansura Huseynova Academician A.M. Guliyev Institute Of Chemistry Of Additives Ministry Of Science And Education Repub, Azerbaycan
Vaqif Farzaliyev Academician A.M. Guliyev Institute Of Chemistry Of Additives Ministry Of Science And Education Repub, Azerbaycan
Ajdar Medjidov
Institute Of Catalysis And Inorganic Chemistry Named After Academician M.Nagiyev Ministry Of Science, Azerbaycan
Mahizar Aliyeva
Academician A.M. Guliyev Institute Of Chemistry Of Additives Ministry Of Science And Education Repub, Azerbaycan
Doç. Dr. Parham Taslimi Bartin Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Bahattin Yalçın Marmara Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2020)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 01-2020
Cilt / Sayı / Sayfa 1200 / 1 / 127082–0 DOI 10.1016/j.molstruc.2019.127082
Makale Linki http://dx.doi.org/10.1016/j.molstruc.2019.127082
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Reaction of zinc nitrate with thiosemicarbazone of glyoxylic acid (H2GAT) leads to the formation of the new complex that have been characterized by spectroscopic methods. Crystal structure of the compound Zn3C18H34N18O17S6 (1) was determined using single crystal X-ray diffraction methods. Single crystal X-ray measurements showed that the complex crystallized in a triclinic system with the space group P-1. The structure of complex 1 presents distorted octahedral geometry around the zinc ion centre. In the crystal structure, Zn(II) ion is coordinated by two nitrogen, two oxygen and two sulfur atoms from two different thiosemicarbazone of glyoxylic acid and two oxygen atoms from two different water molecules. Thermogravimetry shows four steps of decomposition in the temperature range 225–990 °C. This complex was an inhibitor of butyrylcholinesterase (BChE), cytosolic carbonic anhydride I and II isoforms …
Anahtar Kelimeler
Crystal structure | Enzyme inhibition | Thiosemicarbazones | Zn-complex
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 11
Scopus 11
Google Scholar 16
Novel zinc compound with thiosemicarbazone of glyoxylic acid: Synthesis, crystal structure, and bioactivity properties

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