The new metal complex templated polyoxoborate(s) (POB(s)) structures. Synthesis, structural characterization, and hydrogen storage capacities
Yazarlar (4)
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
Arş. Gör. Ömer Yurdakul Hitit Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Dr. Öğr. Üyesi Zeynel Öztürk Hitit University, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2017 |
| Cilt / Sayı / Sayfa | 1134 / 1 / 806–813 | DOI | 10.1016/j.molstruc.2017.01.010 |
| Makale Linki | http://dx.doi.org/10.1016/j.molstruc.2017.01.010 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The polyoxoborate(s) (POB(s)) structures, including a neutral ligand-metal complex compound as a template, were synthesized and the structural characterizations were performed via single crystal X-ray diffraction, FTIR, 11B-NMR, solid state UV–Vis spectroscopy, SEM and elemental analysis methods. Moreover, the stabilization features were determined via TGA/DTA method. In addition, nitrogen and hydrogen adsorption measurements provided the realization to determine the pore size distribution, BET surface area, and hydrogen storage capacities. The molecular formulas of compounds were estimated as [Cu(C12H8N2)2(C2H3O2)][B5O6(OH)4]·2H3BO3·H2O (I) and [Ni(C12H8N2)2(H2O)2]·(B7O9(OH)5)·5H2O (II) and the existence of two different POB(s) structures as pentaborate (B5O6(OH)4) and heptaborate (B7O9(OH)5) within the compounds were observed. At last, it was found that the both structures … |
| Anahtar Kelimeler |
| Crystal structure | Heptaborate | Hydrogen storage | Metal-complex templated polyoxoborates (POB(s)) | Pentaborate | Templated polyoxoborates (POB(s)) | Thermal analysis |
Science Direct
The new metal complex templated polyoxoborate(s) (POB(s)) structures. Synthesis, structural characterization, and hydrogen storage capacities
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 9 |
| Scopus | 11 |
| Google Scholar | 14 |