Synthesis, structural characterization and antimicrobial activity of Schiff bases and benzimidazole derivatives and their complexes with CoCl2, PdCl2, CuCl2 and ZnCl2
Yazarlar (5)
Elham Alterhoni
Istanbul University-Cerrahpasa, Türkiye
Prof. Dr. Aydın Tavman Istanbul University-Cerrahpasa, Türkiye
Doç. Dr. Mayram Hacıoğlu Istanbul Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
A. Seher Birteksöz Tan
Istanbul Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2021)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 04-2021
Cilt / Sayı / Sayfa 1229 / 1 / 1–11 DOI 10.1016/j.molstruc.2020.129498
Makale Linki https://www.sciencedirect.com/science/article/abs/pii/S0022286020318135
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
In this study, new Schiff bases (H2L1 and H2L2) and benzimidazolylphenol derivatives (HL3 − HL5) derived from 5-chlorosalicylaldehyde and appropriate aminophenol and o-phenylenediamine derivatives including 4-methyl/4,5-dimethyl/4-chloro‑5-nitro groups were synthesized and characterized. CoCl2, PdCl2, CuCl2 and ZnCl2 complexes of the ligands were synthesized and characterized by using elemental analysis, molar conductivity, magnetic moment, FT-IR and NMR spectroscopy. In addition, the crystal structure of H2L1 and [Pd(L1)(CH3CN)]·H2O were determined by X-ray diffraction spectroscopy. Keto-enol tautomerism is observed in the Schiff base compounds according to spectral data. Antimicrobial activities of the compounds were tested toward six bacteria and three fungi. Some metal complexes (e.g. Co(II) complexes of the benzimidazole derivatives) showed higher activity towards the test …
Anahtar Kelimeler
Antimicrobial | Benzimidazole | Complex | Phenol | Schiff base | X-ray