Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue
Yazarlar (7)
Mükerrem Fındık
Necmettin Erbakan Üniversitesi, Türkiye
Dr. Öğr. Üyesi Asuman Uçar Ağrı İbrahim Çeçen Üniversitesi, Türkiye
Prof. Dr. Alper Tolga Çolak Kütahya Dumlupınar Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Haluk Bingöl Necmettin Erbakan Üniversitesi, Türkiye
Prof. Dr. Ülkü Sayın Selçuk Üniversitesi, Türkiye
Prof. Dr. Nuriye Koçak Necmettin Erbakan Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polyhedron (Q1)
Dergi ISSN 0277-5387 Dergi Bilgileri (2019)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 03-2019
Cilt / Sayı / Sayfa 160 / 1 / 229–237 DOI 10.1016/j.poly.2018.12.043
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0277538718308490
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
A novel organic–inorganic hybrid of 2,2′-bipyridyl (2,2′-bipy) linked covalently with the first inorganic framework based on boron-containing Keggin-type heteropolymolybdate anion [BMo12O40]5− has been hydrothermally synthesized in aqueous solution. The crystal structure was fully characterized by elemental analyses, single crystal X-ray diffraction, Fourier-transform infrared spectrum (FT-IR), powder X-ray diffraction (XRD), Ultraviolet–visible spectroscopy (UV–Vis) and electron paramagnetic resonance (EPR) analysis. The catalytic performance of the synthesized catalyst was studied in degradation of methylene blue (MB) at ambient temperature. The catalyst exhibited excellent degradation against MB with a rate constant of 0.506/m, which was much higher than those by other polyoxometalate catalysts. Moreover, it was found to be easily separated from the reaction solution and recycled up to five times …
Anahtar Kelimeler
Catalytic degradation | Heteropolymolybdate | Methylene blue | Polyoxometalate | Single crystal structure
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 3
Scopus 3
Google Scholar 6
Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue

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