Synthesis of two Hofmann type and Hofmann-type-like compounds in crystal form from 4-aminopyridine and their characterizations by various methods
Yazarlar (2)
Zeki Kartal
Retired Professor Of Atomic And Molecular Physics, Türkiye
Retired Professor Of Atomic And Molecular Physics, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2022) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2022 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-03-2022 |
| Cilt / Sayı / Sayfa | 1252 / 1 / 132088–0 | DOI | 10.1016/j.molstruc.2021.132088 |
| Makale Linki | http://dx.doi.org/10.1016/j.molstruc.2021.132088 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| This study encompasses the synthesis of two heterometallic tetracyanonickelate(II) complexes based on 4-aminopyridine (4AP) in crystalline form along an investigation of their structural properties. These complexes were characterized by using vibration spectroscopy, elemental analysis, and single crystal X-ray diffraction (SC-XRD) techniques.According to the data obtained using the SC-XRD technique, the heterometallic [Cd(4AP)2Ni(μ4single bondCN)4]n complex has the Triclinic crystal system and the P-1 space group. The other, heterometallic [Ni(4AP)2(H2O)2Ni(μ2single bondCN)2(CN)2]n complex, has Monoclinic crystal system and C2/c space group. The asymmetric unit of heterometallic complex 1 consists of a Ni(II) ion, a Cd(II) ion, two cyanide ligands and a 4AP ligand. Also, the asymmetric unit of complex 2 consists of two Ni(II) ions, a 4AP ligand, two cyanide ligands, and two half coordinated water … |
| Anahtar Kelimeler |
| 4-aminopyridine (4AP) | DFT studies | Hofmann type complexes | Hofmann-type-like complexes | SC-XRD analysis | Vibration spectra |
Science Direct
Synthesis of two Hofmann type and Hofmann-type-like compounds in crystal form from 4-aminopyridine and their characterizations by various methods
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 3 |
| Scopus | 4 |
| Google Scholar | 6 |