Synthesis, spectroscopic, structural characterizations, and catalytic properties of cyanide-bridged heteronuclear metal organic frameworks with imidazole
Yazarlar (5)
Telvin Mwanza
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Hakan Ünver Eskisehir Technical University, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Solid State Chemistry (Q2) | ||
| Dergi ISSN | 0022-4596 Dergi Bilgileri (2022) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2022 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2022 |
| Cilt / Sayı / Sayfa | 314 / 1 / 123344–0 | DOI | 10.1016/j.jssc.2022.123344 |
| Makale Linki | http://dx.doi.org/10.1016/j.jssc.2022.123344 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Three new cyanide-bridged metal complexes of the general formula [Cu2(μ-im)2(im)4M(μ-CN)4]n (where M = Ni(II) for 1, Pd(II) for 2, and Pt(II) for 3; im: imidazole) have been synthesized. All 1–3 were investigated using different and properly chosen physicochemical methods: Fourier transform infrared (FT-IR) and Raman spectroscopies (R), thermal analysis (TG, DTG, DTA), powder and single-crystal X-ray diffraction (PXRD and SC-XRD). The polymeric structures of all complexes crystalize in the same triclinic P-1 space group. Brunauer-Emmett-Teller (BET) method was used for the surface area analysis. The average particle size and morphology were estimated by scanning and transmission electron microscope (SEM and TEM). The heterogeneous catalytic activity of complex 2 catalysts was evaluated on the Suzuki-Miyaura reaction between selected aryl halides and phenyboronic acid. Complex 2 exhibits … |
| Anahtar Kelimeler |
| Heteronuclear complexes | Imidazole complex | Suzuki-Miyaura | Tetracyanonickelate(II) complex | Tetracyanopalladate(II) complex | Tetracyanoplatinate(II) complex |
Science Direct
Synthesis, spectroscopic, structural characterizations, and catalytic properties of cyanide-bridged heteronuclear metal organic frameworks with imidazole
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 11 |
| Scopus | 11 |
| Google Scholar | 14 |