Solvothermal synthesis, crystal structure, thermal, magnetic properties and DFT computations of a Ytterbium(III) complex derived from pyridine-2,6-dicarboxylic acid
Yazarlar (8)
Shahzad Sharif
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Maham Saeed
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
Prof. Dr. Necmi Dege Ondokuz Mayis Üniversitesi, Türkiye
Rehana Bano
University Of The Punjab, Pakistan
University Of The Punjab, Pakistan
Mazhar Amjad Gilani
Comsats Institute Of Information Technology Lahore, Pakistan
Comsats Institute Of Information Technology Lahore, Pakistan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Saeed Ahmad
Prince Sattam Bin Abdulaziz University, Suudi Arabistan
Prince Sattam Bin Abdulaziz University, Suudi Arabistan
Ayoub Rashid Ch
Government College University Lahore, Pakistan
Government College University Lahore, Pakistan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2022) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2022 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-07-2022 |
| Cilt / Sayı / Sayfa | 1260 / 1 / 132877–0 | DOI | 10.1016/j.molstruc.2022.132877 |
| Makale Linki | http://dx.doi.org/10.1016/j.molstruc.2022.132877 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| A new ytterbium(III) complex, (DMAH2)3[Yb(Pydc)3].4H2O (1) {Pydc = Pyridine-2,6-dicarboxylate anion, DMAH2 = Dimethylammonium} has been prepared under mild solvothermal conditions and characterized by elemental analysis, IR spectroscopy, thermal analysis and single crystal X-ray diffraction. The DMAH2 molecules in 1, generated in situ from hydrolysis of N,N-dimethylformamide are responsible to assemble 2D coordination polymer through N-H···O and O-H···O hydrogen bonding. Magnetic susceptibility measurements indicate that the complex (1) obeys the Curie Weiss law and the overall magnetic behavior is typical for the presence of weak antiferromagnetic exchange coupling interactions. Theoretical data for geometrical parameters of complex 1 agree well with the experimental data. Large HOMO-LUMO energy gap of 4.33 eV has provided kinetic stability to the complex 1. NBO analysis reflects that … |
| Anahtar Kelimeler |
| DFT computation | In situ molecules | Magnetic properties | Pyridine-2,6-dicarboxylic acid | Ytterbium(III) |
Science Direct
Solvothermal synthesis, crystal structure, thermal, magnetic properties and DFT computations of a Ytterbium(III) complex derived from pyridine-2,6-dicarboxylic acid
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| Web of Science | 14 |
| Scopus | 14 |
| Google Scholar | 14 |