Nine new tetracyanometallate(II) complexes with 2-(2-aminoethyl)pyridine: synthesis, crystal structures and spectroscopic studies
Yazarlar (4)
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Dr. Öğr. Üyesi Elvan Sayın Turkish Standard Institution (Tse), Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Coordination Chemistry (Q3) | ||
| Dergi ISSN | 0095-8972 Dergi Bilgileri (2022) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2022 |
| Kabul Tarihi | 08-06-2022 | Yayınlanma Tarihi | 19-05-2022 |
| Cilt / Sayı / Sayfa | 75 / 9 / 1352–1373 | DOI | 10.1080/00958972.2022.2096449 |
| Makale Linki | http://dx.doi.org/10.1080/00958972.2022.2096449 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Nine new cyanide complexes, {[Cu(aepy)2M(µ-CN)(CN)3]⋅2H2O}n [M(II) = Ni (1), Pd (2) or Pt (3)], [Zn(aepy)2M(µ-CN)(CN)3]n [M = Ni (4), Pd (5) or Pt (6)] and [Cd(aepy)2M(µ-CN)(CN)3]n [M(II) = Ni (7) or Pd (8)] and (Haepy)2[Pt(CN)4] (9) (aepy = 2-(2-aminoethyl)pyridine), were synthesized and characterized structurally using single crystal X-ray diffraction, vibrational spectroscopy, thermal and elemental analyses. The structure analyses revealed that cyanide complexes 1–3 for Cu(II) and 4–6 for Zn(II) are heterobinuclear clusters, whereas the two Cd(II) complexes 7 and 8 are infinite one-dimensional coordination polymers. In heterometallic complexes 7 and 8, the Cd(II) ions are located on a center of symmetry and are coordinated by two nitrogens from cyanide ligands and four nitrogens from aepy ligands, thus showing a distorted octahedral geometry. In 1–9, the intermolecular N–H⋅⋅⋅N hydrogen bonds or … |
| Anahtar Kelimeler |
| 2-(2-Aminoethyl) pyridine complexes | Cyanide complexes | C–H⋅⋅⋅M interaction | Heteronuclear complexes | Tetracyanometalate(II) complexes |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 3 |
| Google Scholar | 2 |