Cu(II) complex with thiosemicarbazone of glyoxylic acid as an anion ligand in a polymeric structure
Yazarlar (5)
Mansura Teyfur Huseynova
Azerbaijan National Academy Of Sciences, Azerbaycan
Azerbaijan National Academy Of Sciences, Azerbaycan
Mahizar Nacaf Aliyeva
Azerbaijan National Academy Of Sciences, Azerbaycan
Azerbaijan National Academy Of Sciences, Azerbaycan
Ajdar Akber Medjidov Azerbaijan National Academy Of Sciences, Azerbaycan
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Bahattin Yalçın Marmara Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | JOURNAL OF MOLECULAR STRUCTURE (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2019 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2019 |
| Cilt / Sayı / Sayfa | 1176 / 1 / 895–900 | DOI | 10.1016/j.molstruc.2018.08.090 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2018.08.090 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| A new complex of Cu(II), the composition Cu(C3H7N3O4S)∙H2O, the reaction of thiosemicarbazone glyoxylic acid with copper nitrate in an aqueous medium was synthesised. X-ray diffraction analysis established the composition of the complexes was studied by IR, UV electronic absorption and EPR spectroscopy, and thermogravimetry. Thermogravimetry shows five stages of decomposition in the temperature range 90–990°С. The magnetic susceptibility of the complex is studied. The value of μeff for the complex is 1.76 BM, which is close to the value of one unpaired electron (1.73 BM). The ligand coordinates with the metal atom and consists of monoanionic Cu(C3H7N3O4S)∙H2O polymeric complex connected by Cusingle bondN bonds with neighbouring molecules. The metal centre coordinates with the oxygen of carboxylic, sulfur of thiolic and nitrogen of the azomethine group. The X-ray data and ESR spectra … |
| Anahtar Kelimeler |
| Crystal structure | Cu-complex | Thiosemicarbazones |
Science Direct
Cu(II) complex with thiosemicarbazone of glyoxylic acid as an anion ligand in a polymeric structure
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 15 |
| Scopus | 16 |
| Google Scholar | 20 |