N-Alkylation andN-Methylation of Amines with Alcohols Catalyzed by Nitrile-Substituted NHC–Ir(III) and NHC–Ru(II) Complexes
Yazarlar (5)
Arş. Gör. Sinem Çakır Ege Üniversitesi, Türkiye
Serdar Batıkan Kavukcu Ege Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Salih GüNnaz
Ege Üniversitesi, Türkiye
Ege Üniversitesi, Türkiye
Hayati TüRkmen
Ege Üniversitesi, Türkiye
Ege Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | ACS Omega (Q2) | ||
| Dergi ISSN | 2470-1343 Dergi Bilgileri (2023) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 02-2023 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 02-02-2023 |
| Cilt / Sayı / Sayfa | 8 / 6 / 5332–5348 | DOI | 10.1021/acsomega.2c06341 |
| Makale Linki | http://dx.doi.org/10.1021/acsomega.2c06341 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| A series of nitrile-modified N-heterocyclic carbene (NHC) complexes of Ir(III) (2a–e) and Ru(II) (3a–d) have been prepared by transmetallation of [IrCp*Cl2]2 and [RuCl2(p-cymene)]2 forming an in situ NHC–Ag complex. The structures of all complexes were characterized by 1H NMR, 13C NMR, and Fourier transform infrared (FT-IR) spectroscopies. And the structures were clearly elucidated by performing X-ray diffraction studies on 2b, 3a, and 3c single crystals. The complexes of NHC–Ir(III) (2a–e) and NHC–Ru(II) (3a–d) were investigated in the N-alkylation reaction of aniline derivatives with benzyl alcohols to form N-benzyl amines and in the N-methylation reaction of aniline derivatives with methanol. Both reactions were performed in solvent-free media. The Ir(III) complexes (2a–e) were found to perform essentially better than similar Ru(II) complexes (3a–d) in the N-alkylation and N-methylation reactions. Among … |
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BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 17 |
| Scopus | 18 |
| Google Scholar | 20 |