Synthesis, crystal structure and spectroscopic investigations of heteronuclear Co(III)/Cu(II), Co(III)/Cd(II) and Fe(III)/Cd(II) 3D coordination polymers with 4-(2-aminoethyl)pyridine
Yazarlar (4)
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Seray Kekeç
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2023) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 02-2023 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-02-2023 |
| Cilt / Sayı / Sayfa | 1274 / 1 / 134540–0 | DOI | 10.1016/j.molstruc.2022.134540 |
| Makale Linki | http://dx.doi.org/10.1016/j.molstruc.2022.134540 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| The cyanide complexes of transition metals with 4-(2-aminoethyl)pyridine (4aepy) of {[Cu(H2O)(µ-4aepy)Cu(µ-4aepy)2Cu(µ-4aepy)Co2(µ-CN)6(CN)6]·3H2O}n (1), (NH4)[Cd(µ-4aepy)2Co(µ-CN)2(CN)4]n (2) and (NH4)[Cd(µ-4aepy)2Fe(µ-CN)2(CN)4]n (3) were synthesized and investigated by vibrational (FT-IR and Raman), powder X-ray diffraction (PXRD), elemental and thermal analysis techniques. The crystal structures of the complexes have been determined by the single crystal X-ray diffraction (SC-XRD) patterns. The crystallographic analysis reveals that complex 1 crystallizes in the monoclinic system, space group P21, whereas; complexes 2 and 3 crystallize in the tetragonal system, space group P42/ncm. The asymmetric unit of heterometallic complex 1 consists of three Cu(II) ions, two Co(III) ions, four 4aepy ligands, twelve cyanide ligands, one aqua ligand and three non-coordinated water molecules. The … |
| Anahtar Kelimeler |
| 3D complex | 4-(2-aminoethyl)pyridine complex | Coordination polymer | Hexacyanocobaltate(III) complex | Hexacyanoferrate(III) complex |
Science Direct
Synthesis, crystal structure and spectroscopic investigations of heteronuclear Co(III)/Cu(II), Co(III)/Cd(II) and Fe(III)/Cd(II) 3D coordination polymers with 4-(2-aminoethyl)pyridine
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 8 |
| Scopus | 7 |
| Google Scholar | 9 |