Novel copper(II) complexes of two tridentate ONN type ligands: Synthesis, characterization, electrical conductivity and luminescence properties
Yazarlar (5)
Öğr. Gör. Ilyas Gönül Çukurova Üniversitesi, Türkiye
A. Y. Burak
Çukurova Üniversitesi, Türkiye
Öğr. Gör. Serkan Karaca Çukurova Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Selahattin Serin
Çukurova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Inorganica Chimica Acta (Q2)
Dergi ISSN 0020-1693 Dergi Bilgileri (2018)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2018
Kabul Tarihi Yayınlanma Tarihi 01-05-2018
Cilt / Sayı / Sayfa 477 / 1 / 75–83 DOI 10.1016/j.ica.2018.02.026
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0020169317313270
UAK Araştırma Alanları
Yoğun Madde Fiziği
Özet
Herein, we describe the synthesis and characterization of two novel tridentate ONN donor ligands, namely, (E)-2-(((2-(dimethylamino)ethyl)imino)methyl)-6-methoxyphenol (HL1) and (E)-2-(((2-(dimethylamino)ethyl)imino)methyl)-6-ethoxyphenol (HL2), and their copper(II) complexes, [Cu2(L1)2(CH3COO)2] (1), [Cu(L2)(CH3COO)]·2H2O (2). They have been synthesized under conventional methods and characterized by elemental analysis, FT-IR, 1H NMR, 13C NMR, ICP-OES, TGA, DSC and GC/MS analysis. For the morphological analysis field emission scanning electron microscopy (FESEM) was used. The geometry of the Cu(II) complexes was determined by single crystal X-ray diffraction analysis. The Cu(II) ions are in distorted square-pyramidal coordination environments. 1 crystallizes in orthorhombic space group, Pbca, while 2 crystallizes in monoclinic space group, P21/c. Effects of different solvents and …
Anahtar Kelimeler
Copper (II) complexes | Electrical conductivity | Luminescence | Single crystal X-ray | Soluble Schiff base metal complexes