Heteronuclear coordination polymers with imidazole ligand: Synthesis, characterization and alcohol oxidation activities
Yazarlar (6)
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Telvin Mwanza
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Seray Kekeç
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Hakan Ünver Eskisehir Technical University, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q1) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2024) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2024 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-12-2024 |
| Cilt / Sayı / Sayfa | 264 / 1 / 117263–0 | DOI | 10.1016/j.poly.2024.117263 |
| Makale Linki | https://doi.org/10.1016/j.poly.2024.117263 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Two new heteronuclear Cd(II)/Pd(II) coordination polymers, [Cd2(µ-im)2(Him)4Pd(µ-CN)4]n (1) and [Cd(Him)2Pd(µ-CN)4]n (2) (Him: imidazole), have been synthesized under different conditions and characterized using elemental analysis, thermal analysis, FT-IR and Raman spectroscopy, single-crystal and powder X-ray diffraction techniques. In 1, the Cd(II) ions are bridged by imidazolate ligands to generate 1D chain structure. Neighbouring 1D chains were linked by [Pd(CN)4]2- ions to form 3D framework. In 2, the metal ions are bridged by cyanide ligands to generate 2D [Cd2Pd2(µ-CN)4]n network. Catalytic peroxidative oxidation activity of 1 and 2 was examined on the oxidation of benzyl alcohol using tertiary-butyl hydroperoxide (t-BuOOH) as the oxygen source. The compound 1 exhibited over 90 % product conversion at 80 °C in 24-hour reaction time. In addition, the catalyst exhibited high selectivity towards … |
| Anahtar Kelimeler |
| 3D coordination polymer | Alcohol oxidation | Cadmium(II) complex | Imidazole complex | Tetracyanopalladate(II) complex |
Science Direct
Heteronuclear coordination polymers with imidazole ligand: Synthesis, characterization and alcohol oxidation activities
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 2 |
| Google Scholar | 2 |