Heteronuclear Hexacyanometallate(III) Coordination Polymers (Cd/Cr, Cd/Fe, Cd/Co) with 3-(Aminomethyl)pyridine: Synthesis, Characterization, and Catalytic Activities for the Peroxidative Oxidation of Benzylic Alcohols
Yazarlar (5)
Seray Kekeç
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Hakan Ünver Eskisehir Technical University, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials (Q1) | ||
| Dergi ISSN | 1574-1443 Dergi Bilgileri (2024) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2024 |
| Kabul Tarihi | 05-09-2023 | Yayınlanma Tarihi | 04-10-2023 |
| Cilt / Sayı / Sayfa | 34 / 3 / 1081–1091 | DOI | 10.1007/s10904-023-02861-z |
| Makale Linki | https://doi.org/10.1007/s10904-023-02861-z | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| Three new heteronuclear hexacyanometallate(III) coordination polymers (CPs), [Cd3(µ-3ampy)4(H2O)4Cr2(µ-CN)8(CN)4]n (1), [Cd3(µ-3ampy)2(H2O)2Fe2(µ-CN)5(CN)7]n (2) and [Cd3(µ-3ampy)4(H2O)4Co2(µ-CN)8(CN)4]n (3), were synthesized with 3-(aminomethyl)pyridine (3ampy) ligand. All CPs were characterized by FT-IR, Raman, elemental, thermal analysis as well as single crystal X-ray diffraction and powder X-ray diffraction techniques. The single crystal X-ray diffraction analyses shows that the CPs 1 and 3 are two-dimensional structures, whereas CP 2 is a three-dimensional structure where two adjacent metal ions ions are linked via 3ampy and CN bridges. The coordination spheres of all CPs show distorted octahedral geometries. CP 3 was mainly tested as heterogenous catalyst for peroxidative oxidation of benzyl alcohol and its derivatives (4-chloro, 4-bromo, 4-methyl, 4-metoxy and 4-nitro benzyl … |
| Anahtar Kelimeler |
| 2D complex | 3-(Aminomethyl)pyridine complex | 3D complex | Catalyst | Coordination polymer | Hexacyanochromate(III) | Hexacyanocobaltate(III) | Hexacyanoferrate(III) |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 4 |
| Scopus | 3 |
| Google Scholar | 4 |