1D heteronuclear coordination polymers of hexacyanocobaltate(III) with 2-hydroxymethylpyridine
Yazarlar (4)
Seray Kekeç
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q1) | ||
| Dergi ISSN | 0277-5387 Dergi Bilgileri (2024) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2024 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-09-2024 |
| Cilt / Sayı / Sayfa | 260 / 1 / 117096–0 | DOI | 10.1016/j.poly.2024.117096 |
| Makale Linki | https://doi.org/10.1016/j.poly.2024.117096 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| Three new hexacyanocobaltate(III) complexes, {[M2(hmpy)4Co(µ-CN)4(CN)2]∙2H2O}n (M = Cu(II) (1), Zn(II) (2) and Cd(II) (3)) were synthesized with 2-hydroxymethylpyridine (hmpy) ligand, and characterized by vibration (FT-IR and Raman) spectral, single crystal X-ray diffraction (SC-XRD) and powder X-ray diffraction (PXRD), thermal and elemental analyses techniques. The crystallographic analyses revealed that cyanide complexes 1–3 are infinite one-dimensional coordination polymers. Each M ion is coordinated by two nitrogen and two oxygen atoms from the hmpy ligands and two nitrogen atoms from the cyanide ligands, displaying a distorted octahedral coordination geometry. Similarly, each Co(III) ion is coordinated by six carbon atoms from cyanide ligands to form a distorted octahedral coordination geometry. These complexes form 3D supramolecular networks through Osingle bondH···O hydrogen bonds … |
| Anahtar Kelimeler |
| 1D coordination polymer | 2-(hydroxymethyl)pyridine complexes | Cyanide complexes | Hexacyanocobaltate(III) |
Science Direct
1D heteronuclear coordination polymers of hexacyanocobaltate(III) with 2-hydroxymethylpyridine
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 3 |
| Scopus | 3 |
| Google Scholar | 4 |