Comparison of Ru(II)‒arene complexes containing naphthyl-/quinolinyl-substituted ligand vis-a-vis structure, spectra and catalytic activity
Yazarlar (5)
Dr. Öğr. Üyesi Gülşah Türkmen Ege University Faculty Of Engineering, Türkiye
Arş. Gör. Sinem Çakır Ege Üniversitesi, Türkiye
Serdar Batıkan Kavukcu Ege Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Hayati Türkmen Ege Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q2) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2024) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2024 |
| Cilt / Sayı / Sayfa | 1312 / 1 / 138405–0 | DOI | 10.1016/j.molstruc.2024.138405 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2024.138405 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| A series of ligands with naphthyl/quinolinyl substituent in their principal molecular framework were synthesised. Their corresponding half-sandwich ruthenium (Ru) complexes (Ru1a-b, Ru2a-b and Ru3) were then successfully generated. The structure of all synthesised compounds was comprehensively elucidated via 1H and 13C nuclear magnetic resonance (NMR), elemental analysis and Fourier-transform infrared spectroscopies. Notably, the structural configuration of Ru3 was delineated via X-ray diffraction. The catalytic efficacy of the Ru complexes was systematically probed in two distinct reactions: 1) transfer hydrogenation (TH) of ketones using 2-propanol as the hydrogen source and 2) reduction of nitroarenes to anilines using sodium tetrahydridoborate as the reducing agent in ethanol, conducted at ambient temperature. Comparative analysis of catalytic yields of the Ru complexes (Ru1a-b, Ru2a-b and Ru … |
| Anahtar Kelimeler |
| Quinoline/naphthalene derivatives | Reduction of nitroarenes | Ruthenium(II)‒arene complexes | Transfer hydrogenation |
Science Direct
Comparison of Ru(II)‒arene complexes containing naphthyl-/quinolinyl-substituted ligand vis-a-vis structure, spectra and catalytic activity
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 4 |
| Scopus | 4 |
| Google Scholar | 4 |