The mixed ligand complexes of Co(II), Ni(II), Cu(II) and Zn(II) with coumarilic acid/1,10-phenanthroline
Yazarlar (5)
Arş. Gör. Özge Dağlı Hitit University, Türkiye
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
Doç. Dr. Okan İçten Hacettepe Üniversitesi, Türkiye
Prof. Dr. Gülçin Alp Avcı Hitit Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Journal of Thermal Analysis and Calorimetry (Q2) | ||
| Dergi ISSN | 1388-6150 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2019 |
| Kabul Tarihi | 28-09-2018 | Yayınlanma Tarihi | 15-10-2018 |
| Cilt / Sayı / Sayfa | 136 / 4 / 1467–1480 | DOI | 10.1007/s10973-018-7773-y |
| Makale Linki | http://dx.doi.org/10.1007/s10973-018-7773-y | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The coumarilate (coum. sup.-) and 1, 10-phenanthroline (phen) mixed ligand complexes of Co (II)(1), Ni (II)(2) Cu (II)(3) and Zn (II)(4) were synthesized and structural characterizations were performed by using elemental analysis, magnetic susceptibility, solid-state UV-Vis, FTIR spectra, thermoanalytical TG-DTG/DTA and single-crystal X-ray diffraction methods. The Co (II) and Ni (II) complexes are salt-type compounds, and they have two moles phen ligands bound as bidentate, two moles aqua ligands in coordination sphere and two moles anionic coum. sup.-ligand outside of the coordination unit as the counter-ion of the molecular structure. At the same time, the Co (II) and Ni (II) complexes have five moles of aqua ligands as hydrated water outside of the molecules. It was obtained that Cu (II) and Zn (II) complex structures contain one mole of phen ligand, two moles coordinated (coum. sup.-) ligand and a one-mole … |
| Anahtar Kelimeler |
| 1,10-Phenanthroline | Biological application | Coumarilate | Crystal structure | Mixed ligand complexes | Thermal properties |
