Syntheses, crystal structures, spectroscopic and thermal properties of 3D heteronuclear coordination polymers with 4-ethylpyridine and cyanide ligands
Yazarlar (4)
Seray Kekeç
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Structural Chemistry (Q2) | ||
| Dergi ISSN | 1040-0400 Dergi Bilgileri (2024) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 11-2024 |
| Kabul Tarihi | 23-10-2023 | Yayınlanma Tarihi | 04-11-2023 |
| Cilt / Sayı / Sayfa | 35 / 4 / 1075–1083 | DOI | 10.1007/s11224-023-02249-2 |
| Makale Linki | https://doi.org/10.1007/s11224-023-02249-2 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| Three new hexacyanometallate(III) complexes, namely {[Cd3(4epy)12Cr2(µ-CN)6(CN)6]∙4H2O}n (1), {[Cd3(4epy)12Fe2(µ-CN)6(CN)6]∙4H2O}n (2) and {[Cd3(4epy)12Co2(µ-CN)6(CN)6]∙4H2O}n (3), were synthesized by using 4-ethylpyridine (4epy) ligand and characterized by spectral (FT-IR and Raman), crystallographic (SC-XRD and PXRD), thermal and elemental analyses techniques. Single crystal studies have shown that heterometallic complexes 1–3 form 3D polymers. Each M ion [M = Cr(III) in 1, Fe(III) in 2 and Co(III) in 3] is coordinated by six carbon atoms from cyanide ligands and adjacent metal ions are bridged by cyanide ligands to generate [Cd6M6(CN)12] clusters. Each Cd(II) ion is coordinated by four nitrogen atoms from 4epy ligands and two nitrogen atoms from cyanide ligands to distorted octahedral coordination geometry. In addition, thermal (TG/DTA) properties of the complexes were … |
| Anahtar Kelimeler |
| 3D | 4-ethylpyridine | Cadmium(II) | Coordination polymers | Hexacyanochromate(III) | Hexacyanocobaltate(III) | Hexacyanoferrate(III) |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 3 |
| Scopus | 1 |
| Google Scholar | 3 |