One‐Pot hydrothermal synthesis of 1D copper (II) coordination polymers involving in-situ decarboxylation
Yazarlar (3)
B. Ay Çukurova Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Emel Yildiz Çukurova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Solid State Sciences (Q2) | ||
| Dergi ISSN | 1293-2558 Dergi Bilgileri (2019) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2019 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2019 |
| Cilt / Sayı / Sayfa | 96 / 1 / 105958–0 | DOI | 10.1016/j.solidstatesciences.2019.105958 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S1293255819306181 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| One-Dimensional Copper(II) coordination polymers with the formula [Cu(2-pyc)2]n.nH2O (1) (2-Hpyc: Picolinic acid) and [Cu(1,10-phen)(SO4)(H2O)2]n (2) (1,10-phen: 1,10-phenanthroline) have been co-synthesized under hydrothermal conditions in the same medium. The coordination polymers characterized by elemental analysis, FT-IR spectroscopy, TG analysis, ICP-OES, PXRD and single crystal X-ray diffraction. The compound 1 crystallizes in triclinic system, space group P-1, the compound 2 crystallizes in monoclinic system, space group C2/c. In 1, the Cu(II) ions are further joined by picolinic acid ligands, generating 1D coordination polymer running parallel to the [100] direction, while the Cu(II) ions are further joined by sulfate ligands, generating 1D coordination polymer running parallel to the [001] direction in 2. Notably, the 2-Hpyc ligand is in situ generated by decarboxylation of the 2,6 … |
| Anahtar Kelimeler |
| Coordination polymers | Electrical conductivity | Hydrothermal synthesis | In-situ decarboxylation | Luminescence |
Science Direct
One‐Pot hydrothermal synthesis of 1D copper (II) coordination polymers involving in-situ decarboxylation
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 14 |
| Scopus | 15 |
| Google Scholar | 15 |