C–C coupling formation using nitron complexes
Yazarlar (5)
Arş. Gör. Mehmet Sevim Ege Üniversitesi, Türkiye
Arş. Gör. Serdar Batıkan Kavukcu Ege Üniversitesi, Türkiye
Prof. Dr. Armağan Kınal Ege Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Hayati Türkmen Ege Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Dalton Transactions (Q1) | ||
| Dergi ISSN | 1477-9226 Dergi Bilgileri (2020) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2020 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2020 |
| Cilt / Sayı / Sayfa | 49 / 46 / 16903–16915 | DOI | 10.1039/d0dt02937h |
| Makale Linki | https://doi.org/10.1039/d0dt02937h | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| A series of RuII (1), RhIII (2), IrIII (3, 4), IrI (5) and PdII (6–9) complexes of the ‘instant carbene’ nitron were prepared and characterized by 1H- and 13C-NMR, FT-IR and elemental analysis. The molecular structures of complexes 1–4 and 6 were determined by X-ray diffraction studies. The catalytic activity of the complexes (1–9) was evaluated in alpha(α)-alkylation reactions of ketones with alcohol via the borrowing hydrogen strategy under mild conditions. These complexes were able to perform this catalytic transformation in a short time with low catalyst and base amounts under an air atmosphere. Also, the PdII–nitron complexes (6–9) were applied in the Suzuki–Miyaura C–C coupling reaction and these complexes successfully initiated this reaction in a short time (30 minutes) using the H2O/2-propanol (1.5 : 0.5) solvent system. The DFT calculations revealed that the Pd0/II/0 pathway was more preferable for the … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 18 |
| Scopus | 17 |
| Google Scholar | 17 |