The synthesis and structural characterization of transition metal coordination complexes of coumarilic acid
Yazarlar (4)
Arş. Gör. Özge Dağlı Hitit University, Türkiye
Prof. Dr. Dursun Ali Köse Hitit Üniversitesi, Türkiye
Prof. Dr. Onur ŞAHİN Sinop Üniversitesi, Türkiye
Prof. Dr. Zarife Sibel ŞAHİN Sinop Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Thermal Analysis and Calorimetry (Q2) | ||
| Dergi ISSN | 1388-6150 Dergi Bilgileri (2017) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2017 |
| Cilt / Sayı / Sayfa | 128 / 3 / 1373–1383 | DOI | 10.1007/s10973-016-6053-y |
| Makale Linki | http://link.springer.com/10.1007/s10973-016-6053-y | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
|
||
| Özet |
| The coumarilate (coum−) complexes of CoII(1), NiII(2) CuII(3) and ZnII(4) were synthesized and characterized by elemental analysis, magnetic susceptibility, solid-state UV–Vis, FTIR spectra, thermoanalytical TG–DTG/DTA and single-crystal X-ray diffraction methods. It was found that all of the complex structures have 2 mol (coum−) ligand bonded as monoanionic monodentate in the structures of 1 and 2 while they were coordinated to metal cations as monoanionic bidentate in the complexes 3 and 4. There was not any hydrate water in the metal complexes. The complexes of 1 and 2 have four moles of aqua ligand, and the other complexes have two moles. Thermal decomposition of each complex starts with dehydration, and then the decomposition of organic parts goes. The thermal dehydration of the complexes takes place in one (for the compounds of 2, 3, 4) or two (for the compound 1) steps. The decomposition … |
| Anahtar Kelimeler |
| Coumarilate | Crystal structure | Metal complexes | Structural analysis | Thermal analysis |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 14 |
| Scopus | 16 |
| Google Scholar | 19 |