Theoretical and experimental investigations on the nonlinear optical properties of gold III dithiolene complexes
Yazarlar (10)
I. Guezguez Institut Des Sciences Et Technologies Moléculaires D'angers, Fransa
A. Karakas
Selçuk Üniversitesi, Türkiye
K. Iliopoulos Institut Des Sciences Et Technologies Moléculaires D'angers, Fransa
B. Derkowska-Zielinska
Uniwersytet Mikołaja Kopernika W Toruniu, Polonya
A. El-Ghayoury Institut Des Sciences Et Technologies Moléculaires D'angers, Fransa
A. Ranganathan Institut Des Sciences Et Technologies Moléculaires D'angers, Fransa
P. Batail Institut Des Sciences Et Technologies Moléculaires D'angers, Fransa
A. Migalska-Zalas Katedra Fizyki Ciała Stałego Akademia Im., Polonya
B. Sahraoui Institut Des Sciences Et Technologies Moléculaires D'angers, Fransa
Prof. Dr. Mustafa KARAKAYA Sinop Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Optical Materials (Q2)
Dergi ISSN 0925-3467 Dergi Bilgileri (2014)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2014
Kabul Tarihi Yayınlanma Tarihi 01-11-2013
Cilt / Sayı / Sayfa 36 / 1 / 106–111 DOI 10.1016/j.optmat.2013.04.037
Makale Linki http://www.sciencedirect.com/science/journal/09253467
UAK Araştırma Alanları
Atom, Molekül ve Lazer Fiziği
Özet
Degenerate four-wave mixing (DFWM) experiments have been performed to determine the third-order nonlinear optical (NLO) susceptibilities (χ (3)) of gold (III) maleimide dithiolate tetraphenylphosphonium,(PPh 4)[Au (midt) 2],(Au-P) and gold (III) maleimide dithiolate melamine melaminium hybrid solvate,(C 3 N 6 H 6)(C 3 N 6 H 7+)[Au (midt) 2]−· 2DMF· 2H 2 O,(Au-Mel). Ab-initio quantum mechanical calculations (time-dependent Hartree–Fock (TDHF) method) of Au-P and Au-Mel have been carried out to compute the electric dipole moment (μ), the dispersion-free and frequency-dependent dipole polarizability (α) and the second hyperpolarizability (γ) values. These theoretical calculations are in good agreement with the experimentally obtained results by the DFWM technique. All the investigations show clearly the effect played by the counter ion on the resulting NLO properties of the two gold complexes.
Anahtar Kelimeler
Degenerate four wave mixing | Dithiolene complexes | Nonlinear optical response | Time-dependent Hartree-Fock
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 17
Scopus 16
Google Scholar 20
Theoretical and experimental investigations on the nonlinear optical properties of gold III dithiolene complexes

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