Kinetic and equilibrium studies of methylene blue adsorption on functionalized polymethyl methacrylate in polyvinylidene fluoride–hexafluoropolypropylene matrix
Yazarlar (2)
Prof. Dr. Kinyas POLAT Sinop Üniversitesi, Türkiye
E. A. Bursali
Dokuz Eylül Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı International Journal of Environmental Science and Technology (Q3)
Dergi ISSN 1735-1472 Dergi Bilgileri (2021)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2021
Kabul Tarihi 06-01-2021 Yayınlanma Tarihi 24-01-2021
Cilt / Sayı / Sayfa 18 / 12 / 3943–3950 DOI 10.1007/s13762-021-03133-4
Makale Linki http://dx.doi.org/10.1007/s13762-021-03133-4
UAK Araştırma Alanları
Fiziksel Kimya
Özet
Herein a novel polymeric adsorbent composite material was introduced for the adsorption of methylene blue from aqueous solutions for the purpose of water treatment. Adsorption process was examined by using Langmuir and Freundlich isotherm models together with pseudo-first and second order kinetic analysis. It was found that characteristic of the adsorption process was well described by Langmuir isotherm following pseudo-first order kinetic route. The maximum monolayer adsorption capacity was determined as 49.04 mg g−1. In light of thermodynamic parameters of the adsorption and removal of MB from the composite in acidic solution suggested that the process was based on ion-exchange mechanism. Negative values of Gibbs free energies changing from − 5.41 to − 15.99 kJ mol−1 with increasing temperature demonstrated that adsorption process occurs spontaneously. Heat of adsorption and entropy …
Anahtar Kelimeler
Langmuir | Polymer composite | pseudo-first order kinetic | Waste water